An elaborate low-temperature electrolyte design towards high-performance liquid metal battery
نویسندگان
چکیده
Liquid metal battery (LMB) with low cost, excellent cycle performance and flexible scalability is developed as a promising solution for large-scale energy storage. However, the high melting point of electrolyte necessitates an elevated operating temperature, which provokes aggravated hermetic seal corrosion issues, seriously inhibiting advancement LMBs. Herein, we elaborately design novel LiCl–LiBr–KBr system based on mass triangle model to overcome this obstacle. The LiCl LiBr components can provide required lithium ionic conduction, while KBr plays dual role decreasing suppressing dissolution. designed (33:29:38 mol%) possesses (Tm = 327 °C), conductivity (1.573 S cm−1 at 420 enables Li||Bi work efficiently °C efficiency (83%), rate capability, superior cycling stability freeze/thaw performance. This represents 80–130 decrease in temperature compared most reported unique combination together its cost makes extremely attractive low-temperature LMB.
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ژورنال
عنوان ژورنال: Journal of Power Sources
سال: 2022
ISSN: ['1873-2755', '0378-7753']
DOI: https://doi.org/10.1016/j.jpowsour.2022.231527